High efficiency desulfurization catalyst in natural rubber, together with sulfur yellow, can prevent vulcanization reversion, improve heat resistance, reduce heat generation, aging resistance, improve rubber and cord adhesion and vulcanization rubber modulus. It is used in the rubber of shoulder rubber and cushion layer of load tires, which can solve the problem of shoulder hollow of slant load tires, and also can be used in the large-size thick products of natural rubber and various rubber miscellaneous products.